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- Title
Synthesis of Oxaphosphinane-Based Pseudodisaccharides.
- Authors
Babouri, Rachida; Clarion, Ludovic; Rolland, Marc; Van der Lee, Arie; Kabouche, Zahia; Volle, Jean‐Noël; Virieux, David; Pirat, Jean‐Luc
- Abstract
The synthesis of pseudodisaccharides based on an oxaphosphinane heterocycle is described. Disaccharide mimetics 5 and 6 were readily obtained through glycosylation of a hydroxy group with appropriately protected furanosyl or pyranosyl carbohydrates using a trichloroacetamidate coupling strategy. Selective or complete deprotection then produced the chiral pseudodisaccharides in good yields.
- Subjects
PHOSPHINES; DISACCHARIDES synthesis; HETEROCYCLIC compounds; GLYCOSYLATION; CARBOHYDRATES
- Publication
European Journal of Organic Chemistry, 2017, Vol 2017, Issue 36, p5357
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201700878