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- Title
Synthesis and X-ray Structural Characterization of the Polymeric Cluster Compound [Hg<sub>3</sub>(O<sub>2</sub>SePh)(SePh)<sub>5</sub>] <sub>n</sub>.
- Authors
Stieler, Rafael; Back, Davi F.; Tirloni, Bárbara; Burrow, Robert A.; Lang, Ernesto S.
- Abstract
Two synthetic routes to prepare [Hg3(O2SePh)(SePh)5] n and its structural characterization are presented in this paper. This compound results either from the partial oxidation of mercury phenylselenolate clusters or from a mixture of its components with defined stoichiometry. This compound was observed in almost all of our reactions as a by-product, during the development of the synthesis of new mercury selenolate clusters. It was now characterized by single-crystal X-ray diffractometry, elemental analysis, and infrared spectroscopy.
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2012, Vol 638, Issue 10, p1501
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201200257