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- Title
Iron-Catalyzed Michael Addition of Ketones to Polar Olefins.
- Authors
Zhang, Di ‐ Han; Knelles, Jakob; Plietker, Bernd
- Abstract
The base metal complex tetrabutylammonium nitrosyltricarbonylferrate {Bu4N[Fe(CO)3(NO)] (TBA[Fe])} - catalyzes the conjugate addition of ketones to polar olefins. The reaction is applicable to a wide range of substrates leading to interesting building blocks for organic synthesis. Clear indications for an acid-base type rather than a C−H activation pathway exist.
- Subjects
KETONES; ALKENES; AMMONIUM; CARBONYL compounds; ORGANIC synthesis
- Publication
Advanced Synthesis & Catalysis, 2016, Vol 358, Issue 15, p2469
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201600278