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- Title
Gold(I)/Copper(II)-Cocatalyzed Tandem Cyclization/Semipinacol Reaction: Construction of 6- Aza/Oxa-Spiro[4.5]decane Skeletons and Formal Synthesis of (±)-Halichlorine.
- Authors
Zhu, Dao ‐ Yong; Zhang, Zhen; Mou, Xue ‐ Qing; Tu, Yong ‐ Qiang; Zhang, Fu ‐ Min; Peng, Jin ‐ Bao; Wang, Shao ‐ Hua; Zhang, Shu ‐ Yu
- Abstract
A simple and efficient strategy for the construction of 6- aza/oxa-spiro[4.5]decane skeletons under the cocatalysis of gold(I)/copper(II) was developed, and its potential utility was demonstrated by a formal synthesis of the biologically active marine alkaloid (±)-halichlorine.
- Subjects
GOLD catalysts; COPPER catalysts; RING formation (Chemistry); AZA compounds; CHLORINE
- Publication
Advanced Synthesis & Catalysis, 2015, Vol 357, Issue 4, p747
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201400932