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- Title
Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates.
- Authors
Candy, Mathieu; Rousseaux, Sophie A. L.; San Román, Alberto Cirugeda; Szymczyk, Monika; Kafarski, Pawel; Leclerc, Eric; Vrancken, Emmanuel; Campagne, Jean ‐ Marc
- Abstract
The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported.
- Subjects
PALLADIUM catalysts; ALKENES; ENAMINES; PHOSPHONATES; ALKYL compounds
- Publication
Advanced Synthesis & Catalysis, 2014, Vol 356, Issue 11/12, p2703
- ISSN
1615-4150
- Publication type
Other
- DOI
10.1002/adsc.201400190