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- Title
[Ge<sub>12</sub>{FeCp(CO)<sub>2</sub>}<sub>8</sub>{FeCp(CO)}<sub>2</sub>]: A Ge<sub>12</sub> Core Resembles the Arrangement of the High-Pressure Modification Germanium (II).
- Authors
Schenk, Christian; Henke, Florian; Schnepf, Andreas
- Abstract
Similar yet different: The reaction of a GeBr solution with K[FeCp(CO)2] (Cp=η‐C5H5) gives [Ge12{FeCp(CO)2}8{FeCp(CO)}2] (1), whose oblong, highly cross‐linked cluster core reveals a cut‐out of the high‐pressure solid‐state structure of germanium (II) (see scheme). Mass spectrometric investigations on the gas‐phase species [Ge6{FeCp(CO)2}6{FeCp(CO)}]− (2) and theoretical calculations on 1 and 2 illuminate the formation of the metalloid cluster 1.
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 6, p1834
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201207224