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- Title
Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π-π Stacking Interactions.
- Authors
Zhou, You‐Yun; Li, Jun; Ling, Lin; Liao, Sai‐Hu; Sun, Xiu‐Li; Li, Yu‐Xue; Wang, Li‐Jia; Tang, Yong
- Abstract
Designing armory: The side‐arm‐modified In‐TOX/NiII complex was identified as a highly efficient and stereoselective catalyst for the [3+3] cycloaddition of aromatic azomethine imines with cyclopropanes (see picture). Density functional calculations and control experiments revealed that the directing effect of the side arm through π interactions is crucial to the stereochemical control.
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 5, p1452
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201207576