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- Title
Organic Salts as a Route to Energy Level Control in Low Bandgap, High Open-Circuit Voltage Organic and Transparent Solar Cells that Approach the Excitonic Voltage Limit.
- Authors
Suddard‐Bangsund, John; Traverse, Christopher J.; Young, Margaret; Patrick, Tyler J.; Zhao, Yimu; Lunt, Richard R.
- Abstract
A new series of organic salts with selective near-infrared (NIR) harvesting to 950 nm is reported, and anion selection and blending is demonstrated to allow for fine tuning of the open-circuit voltage. Extending photoresponse deeper into the NIR is a significant challenge facing small molecule organic photovoltaics, and recent demonstrations have been limited by open-circuit voltages much lower than the theoretical and practical limits. This work presents molecular design strategies that enable facile tuning of energy level alignment and open-circuit voltages in organic salt-based photovoltaics. Anions are also shown to have a strong influence on exciton diffusion length. These insights provide a clear route toward achieving high efficiency transparent and panchromatic photovoltaics, and open up design opportunities to rapidly tailor molecules for new donor-acceptor systems.
- Subjects
SOLAR cells; SALTS; CHEMISTRY; ELECTRIC potential; PHOTOVOLTAIC cells
- Publication
Advanced Energy Materials, 2016, Vol 6, Issue 1, pn/a
- ISSN
1614-6832
- Publication type
Article
- DOI
10.1002/aenm.201501659