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- Title
Zephyranthes-like Co<sub>2</sub>NiSe<sub>4</sub> arrays grown on 3D porous carbon frame-work as electrodes for advanced supercapacitors and sodium-ion batteries.
- Authors
Xue, Yanchun; Guo, Xingmei; Wu, Mengrong; Chen, Jiale; Duan, Mengting; Shi, Jing; Zhang, Junhao; Cao, Fu; Liu, Yuanjun; Kong, Qinghong
- Abstract
Developing suitable electrode materials for electrochemical energy storage devices by biomorph assisted design has become a fascinating topic due to the fantastic properties derived from bio-architectures. Herein, zephyranthes-like Co2NiSe4 arrays grown on butterfly wings derived three-dimensional (3D) carbon framework (Z-Co2NiSe4/BWC) is fabricated via hydrothermal assembly and further conversion method. Benefiting from its unique structure and multi-components, the obtained Z-Co2NiSe4/BWC electrode for supercapacitor delivers an excellent specific capacitance of 2,280 F·g−1 at 1 A·g−1. Impressively, the constructed asymmetric supercapacitor using Co2NiSe4/BWC as positive electrode and activated butterfly wings carbon as negative electrode acquires a high energy density of 42.9 Wh·kg−1 at a power density of 800 W·kg−1 with robust stability of 94.6% capacitance retention at 10 A·g−1 after 5,000 cycles. Moreover, the Z-Co2NiSe4/BWC as anode for sodium-ion batteries exhibits a high specific capacity of 568 mAh·g−1 at 0.1 A·g−1 and high cycling stability (maintaining 80.1% of the second cycle after 100 cycles). The outstanding electrochemical performances are ascribed to that the synergistic effect of bimetallic selenides and N-doped carbon improves electrochemical activities and conductivity. One-dimensional (1D) nanoneedles grown on 3D porous framework increase the exposure of redox-active sites, endow adequate transmission channels of electrons/ions, and guarantee stability of the electrode during charge/discharge processes. This study will shed light on the avenue towards extending such nanohybrids to excellent energy storage applications.
- Publication
Nano Research, 2021, Vol 14, Issue 10, p3598
- ISSN
1998-0124
- Publication type
Article
- DOI
10.1007/s12274-021-3640-4