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- Title
PREPARATION AND REDUCTIVE ELIMINATION OF DIGERMYLPLATINUM COMPLEXES.
- Authors
Mochida, Kunio; Wada, Tohru; Hatanaka, Wakako; Nishiyama, Yuriko; Suzuki, Michiko; Nanjo, Masato
- Abstract
cis- and irans-(R3Ge)2Pt(PMe2Ph)2 complexes as key intermediates of bis-germylation of alkynes have been prepared, and their structures have been established by spectroscopic methods and X-ray crystallography. The cis isomers afford digermanes, (R3Ge)2 as reductive elimination products in good yields. In contrast, the trans isomers lead to monogermanes.
- Publication
Main Group Metal Chemistry, 2001, Vol 24, Issue 9, p647
- ISSN
0792-1241
- Publication type
Article