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- Title
Cover Feature: Molecular Basis of the Chemiluminescence Mechanism of Luminol (Chem. Eur. J. 20/2019).
- Authors
Giussani, Angelo; Farahani, Pooria; Martínez‐Muñoz, Daniel; Lundberg, Marcus; Lindh, Roland; Roca‐Sanjuán, Daniel
- Abstract
Quantum‐chemistry determinations of the luminol chemiluminescence mechanism have made it possible to: first, clarify the spin inversion of the reaction; secondly, to determine the concerted nature of the two steps of 3O2 addition and 1N2 elimination; thirdly, to answer why such oxygen by nitrogen substitution must occur for an efficient excited‐state population; fourthly, to describe the electronic‐structure properties of the chemiexcitation; and finally, to distinguish the paths producing light emission versus those giving rise to radiationless decay. More information can be found in the Full Paper by A. Giussani, D. Roca‐Sanjuán, et al. on page 5202.
- Subjects
LUMINOL; CHEMIEXCITATION; CHARGE exchange
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 20, p5102
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201900874