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- Title
Efficient 1400–1600 nm Circularly Polarized Luminescence from a Tuned Chiral Erbium Complex.
- Authors
Willis, Oliver G.; Petri, Filippo; Pescitelli, Gennaro; Pucci, Andrea; Cavalli, Enrico; Mandoli, Alessandro; Zinna, Francesco; Di Bari, Lorenzo
- Abstract
Novel chiral Er complexes based on both enantiomers of extended iPrPyBox (2,6‐Bis[4‐isopropyl‐4,5‐dihydrooxazol‐2‐yl)]pyridine) show strong near‐infrared circularly polarized luminescence (CPL) within the 1400 to 1600 nm spectral region under 450 nm irradiation. CPL activity in this region, despite being particularly rare, would open the way to potential applications in the domain, e.g., of fiber‐optic telecommunications and free‐space long‐distance optical communications employing circularly polarized light. Moreover, the long wavelength excitation is advantageous for applications in the field of (circularly polarized) microscopy and bioimaging.
- Subjects
ERBIUM; FREE-space optical technology
- Publication
Angewandte Chemie, 2022, Vol 134, Issue 34, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202208326