We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN.
- Authors
Hu, Xin; Cui, Guopeng; Zhu, Ning; Zhai, Jinglin; Guo, Kai
- Abstract
Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence ofMe6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by "off-on" impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP.
- Subjects
PHOTOINDUCED electron transfer; POLYMERIZATION; COPPER catalysts; POLYACRYLONITRILES; POLYACRYLATES
- Publication
Polymers (20734360), 2018, Vol 10, Issue 1, p68
- ISSN
2073-4360
- Publication type
Article
- DOI
10.3390/polym10010068