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- Title
Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size.
- Authors
Egleston, Benjamin D.; Luzyanin, Konstantin V.; Brand, Michael C.; Clowes, Rob; Briggs, Michael E.; Greenaway, Rebecca L.; Cooper, Andrew I.
- Abstract
Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe‐selective to CH4‐selective, which is understood using 129Xe, 1H, and pulsed‐field gradient NMR spectroscopy.
- Subjects
NUCLEAR magnetic resonance spectroscopy; LIQUIDS; CHEMICAL synthesis; GASES
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 19, p7432
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201914037