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- Title
High iso Aldehyde Selectivity in the Hydroformylation of Short‐Chain Alkenes.
- Authors
Iu, Leo; Fuentes, José A.; Janka, Mesfin E.; Fontenot, Kevin J.; Clarke, Matthew L.
- Abstract
The hydroformylation of propene to give predominantly iso‐butanal has been achieved; class‐leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos‐biphenols and unusual solvent systems are the key to the selectivity observed.
- Subjects
ALKENES; HYDROFORMYLATION; RACEMIC mixtures; RHODIUM compounds; METAL complexes; PHOSPHOLANES
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 7, p2142
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201811888