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- Title
Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen-Bonded Anions.
- Authors
Cavallo, Gabriella; Terraneo, Giancarlo; Monfredini, Alessandro; Saccone, Marco; Priimagi, Arri; Pilati, Tullio; Resnati, Giuseppe; Metrangolo, Pierangelo; Bruce, Duncan W.
- Abstract
Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen-bonded supramolecular anions [C nF2 n+1-I⋅⋅⋅I⋅⋅⋅I-C nF2 n+1]− are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen-bonded liquid crystals, and 2) imidazolium-based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation.
- Subjects
IONIC liquids; CRYSTALLINITY; HALOGEN compounds; SUPRAMOLECULAR chemistry; LIQUID crystals
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 21, p6408
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201601278