We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Palladium-Catalyzed Oxidative Synthesis of α-Acetoxylated Enones from Alkynes.
- Authors
Jiang, Tuo; Quan, Xu; Zhu, Can; Andersson, Pher G.; Bäckvall, Jan ‐ E.
- Abstract
We report a palladium-catalyzed oxidative functionalization of alkynes to generate α-acetoxylated enones in one step. A range of functional groups are well-tolerated in this reaction. Mechanistic studies, including the use of 18O-labeled DMSO, revealed that the ketone oxygen atom in the product originates from DMSO.
- Subjects
PALLADIUM; ALKYNES; OXIDATION; KETONES; FUNCTIONAL groups
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 19, p5918
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201600696