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- Title
Selective Michael Reaction Controlled by Supersilyl Protecting Group.
- Authors
Izumiseki, Atsuto; Yamamoto, Hisashi
- Abstract
Selective Michael reaction of organolithium reagents to supersilyl methacrylate is reported. The method was able to control a single and double Michael addition. The successful termination of the process using the supersilyl protecting group allows for the controlled, chemoselective, and diastereoselective Michael reaction.
- Subjects
MICHAEL reaction; ORGANOLITHIUM compounds; METHACRYLATES; CHEMOSELECTIVITY; STEREOSELECTIVE reactions
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 30, p8821
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201503574