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- Title
Synthesis of Heterocycles through Transition-Metal-Catalyzed Isomerization Reactions.
- Authors
Ishoey, Mette; Nielsen, Thomas E.
- Abstract
Metal-catalyzed isomerization of N- and O-allylic systems is emerging as an effective method to form synthetically useful iminium and oxocarbenium intermediates. In the presence of tethered nucleophiles, several recent examples illuminate this approach as a powerful strategy for the synthesis of structurally complex and diverse heterocycles. In this Concept article, we attempt to cover this area of research through a selection of recent versatile examples.
- Subjects
HETEROCYCLIC compounds; TRANSITION metals; CHEMICAL synthesis; ISOMERIZATION; NUCLEOPHILES
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 29, p8832
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201400216