We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
A Stable Microporous Mixed-Metal Metal–Organic Framework with Highly Active Cu<sup>2+</sup> Sites for Efficient Cross-Dehydrogenative Coupling Reactions.
- Authors
Yang, Xiu‐Li; Zou, Chao; He, Yabing; Zhao, Min; Chen, Banglin; Xiang, Shengchang; O'Keeffe, Michael; Wu, Chuan‐De
- Abstract
Two metalloporphyrin octacarboxylates were used to link copper(II) nodes for the formation of two novel porous mixed-metal metal–organic frameworks (M'MOFs) containing nanopore cages (2.1 nm in diameter) or nanotubular channels (1.5 nm in diameter). The highly active Cu2+ sites on the nanotubular surfaces of the stable porous M'MOF ZJU-22, stabilized by three-connected nets, lead to the superior catalytic activity for the cross-dehydrogenative coupling (CDC) reaction.
- Subjects
METAL-organic frameworks; COPPER; COORDINATION polymers; CRYSTAL structure; X-ray diffraction
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 5, p1447
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201303615