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- Title
Recognition of Chiral Amines by a Terpyridine-Zn<sup>II</sup>-Complex-Based Circular-Dichroism Sensor.
- Authors
Chen, Liming; Yu, Shanshan; Xiao, Meng; Huang, Zeng; Wen, Kaili; Xu, Yimang; Zhao, Feng; Yu, Xiaoqi; Pu, Lin
- Abstract
A terpyridine-based aldehyde was discovered to exhibit strong circular-dichroism (CD) signals at wavelengths much greater than the absorptions of the chiral substrates when treated with chiral amines, amino alcohols, and amino acids in the presence of Zn2+. This sensor system can be used to determine the enantiomeric composition of the chiral compounds by CD measurement.
- Subjects
MOLECULAR recognition; AMINES; PYRIDINE; ZINC compounds; METAL complexes; CIRCULAR dichroism; ALDEHYDES
- Publication
European Journal of Organic Chemistry, 2017, Vol 2017, Issue 16, p2338
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201700066