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- Title
Merging N‐Hydroxyphthalimide into Metal‐Organic Frameworks for Highly Efficient and Environmentally Benign Aerobic Oxidation.
- Authors
Wang, Man; Liang, Gan; Wang, Yunhao; Fan, Tao; Yuan, Baoling; Liu, Mingxian; Yin, Ying; Li, Liangchun
- Abstract
Two highly efficient metal‐organic framework catalysts TJU‐68‐NHPI and TJU‐68‐NDHPI have been successfully synthesized through solvothermal reactions of which the frameworks are merged with N‐hydroxyphthalimide (NHPI) units, resulting in the decoration of pore surfaces with highly active nitroxyl catalytic sites. When t‐butyl nitrite (TBN) is used as co‐catalyst, the as‐synthesized MOFs are demonstrated to be highly efficient and recyclable catalysts for a novel three‐phase heterogeneous oxidation of activated C−H bond of primary and secondary alcohols, and benzyl compounds under mild conditions. Based on the high efficiency and selectivity, an environmentally benign system with good sustainability, mild conditions, simple work‐up procedure has been established for practical oxidation of a wide range of substrates.
- Subjects
CATALYSTS; METAL-organic frameworks; BENZYL compounds; CATALYSTS recycling; OXIDATION; ALCOHOL; NITROXYL
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 37, p9674
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202100987