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- Title
Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Constructed by Bis(4-(1H-Imidazol-1-yl)phenyl) Methanone and 1,4-Benzenedicarboxylate Ligands.
- Authors
Wang, G.-F.; Sun, S.-W.; Sun, H.; Song, S.-F.; Jiang, H.-S.
- Abstract
A coordination polymer with the V-shaped ligands, {Cd2(bipmo)2(bdc)2⋅H2O}n (1), (where bipmo is bis(4-(1H-imidazol-1-yl)phenyl)methanone; H2bdc is 1,4-benzenedicarboxylic acid) has been prepared and structural characterized by IR, elemental analyses and single-crystal X-ray diffraction. X-ray diffraction analyses show that the Cd(II) ion is in a distorted octahedral environment, of which the donor atoms are provided by oxygen atoms of the bdc2– ligands and nitrogen atoms of the bipmo ligands. From a topological point of view, the framework of 1 exhibits two-fold 3D uninodal six-connected interpenetrating framework with the (412 ⋅ 63) pcu topology.
- Subjects
COORDINATION polymers; LIGANDS (Chemistry); CRYSTAL structure; ELEMENTAL analysis; CADMIUM; X-ray diffraction
- Publication
Crystallography Reports, 2021, Vol 66, Issue 7, p1253
- ISSN
1063-7745
- Publication type
Article
- DOI
10.1134/S1063774521070208