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- Title
Water Transport with Ultralow Friction through Partially Exfoliated g-C<sub>3</sub>N<sub>4</sub> Nanosheet Membranes with Self-Supporting Spacers.
- Authors
Wang, Yanjie; Li, Libo; Wei, Yanying; Xue, Jian; Chen, Huang; Ding, Li; Caro, Jürgen; Wang, Haihui
- Abstract
Two-dimensional (2D) graphitic carbon nitride (g-C3N4) nanosheets show brilliant application potential in numerous fields. Herein, a membrane with artificial nanopores and self-supporting spacers was fabricated by assembly of 2D g-C3N4 nanosheets in a stack with elaborate structures. In water purification the g-C3N4 membrane shows a better separation performance than commercial membranes. The g-C3N4 membrane has a water permeance of 29 L m−2 h−1 bar−1 and a rejection rate of 87 % for 3 nm molecules with a membrane thickness of 160 nm. The artificial nanopores in the g-C3N4 nanosheets and the spacers between the partially exfoliated g-C3N4 nanosheets provide nanochannels for water transport while bigger molecules are retained. The self-supported nanochannels in the g-C3N4 membrane are very stable and rigid enough to resist environmental challenges, such as changes to pH and pressure conditions. Permeation experiments and molecular dynamics simulations indicate that a novel nanofluidics phenomenon takes place, whereby water transport through the g-C3N4 nanosheet membrane occurs with ultralow friction. The findings provide new understanding of fluidics in nanochannels and illuminate a fabrication method by which rigid nanochannels may be obtained for applications in complex or harsh environments.
- Subjects
MARITIME shipping; FRICTION; ARTIFICIAL membranes; NITRIDES; WATER purification; SEPARATION (Technology)
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 31, p9102
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201701288