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- Title
Rhodium(I)-Catalyzed Tertiary Phosphine Directed C−H Arylation: Rapid Construction of Ligand Libraries.
- Authors
Qiu, Xiaodong; Wang, Minyan; Zhao, Yue; Shi, Zhuangzhi
- Abstract
Modification of commercially available monophosphine ligands with either aryl bromides or chlorides by rhodium(I)-catalyzed, tertiary phosphine directed C−H activation is described. A series of ligand libraries containing mono- and diaryl-substituted groups, having different steric and electronic properties, were obtained in high yields. Based on the outstanding properties of their parent scaffolds, the modified ligands have been found to be powerful in organic reactions.
- Subjects
RHODIUM; LIGANDS (Chemistry); CHEMICAL reactions; SCAFFOLDING; BROMIDES
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 25, p7339
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201703354