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- Title
Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene-Stabilized Borenium Catalysts.
- Authors
Eisenberger, Patrick; Bestvater, Brian P.; Keske, Eric C.; Crudden, Cathleen M.
- Abstract
1,2,3-Triazolylidene-based mesoionic carbene boranes have been synthesized in a convenient one-pot protocol from the corresponding 1,2,3-triazolium salts, base, and borane. Borenium ions are obtained by hydride abstraction and serve as catalysts in mild hydrogenation reactions of imines and unsaturated N-heterocycles at ambient pressure and temperature.
- Subjects
THERMOMETERS; THERMAL properties; ISOTHERMAL processes; BUYS-Ballot's laws; ADSORPTION isobars
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 8, p2497
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201409250