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- Title
Synthesis and Structural Characterization of 2:1 [α/Aza]-oligomers.
- Authors
Zhou, Zhou; Deng, Cheng; Abbas, Cécile; Didierjean, Claude; Averlant‐Petit, Marie‐Christine; Bodiguel, Jacques; Vanderesse, Régis; Jamart‐Grégoire, Brigitte
- Abstract
The design of a new β-turn inducer is correlated to the discovery of new foldamers. In this paper, we report the liquid phase synthesis of 2:1 [α/aza]-oligomers using a convergent Boc strategy. The NMR, FTIR, restrained molecular dynamics and X-ray diffraction analyses show that 2:1 [α/aza]-oligomers adopt a C=O( i) ···H-N( i + 2) hydrogen-bonded helical conformation.
- Subjects
OLIGOMERIZATION; X-ray diffraction; MOLECULAR dynamics; CONFORMATIONAL analysis; HYDROGEN bonding
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 34, p7643
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201402628