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- Title
Room Temperature CP Bond Formation Enabled by Merging Nickel Catalysis and Visible-Light-Induced Photoredox Catalysis.
- Authors
Xuan, Jun; Zeng, Ting-Ting; Chen, Jia-Rong; Lu, Liang-Qiu; Xiao, Wen-Jing
- Abstract
A novel and efficient CP bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and visible-light-induced photoredox catalysis. This dual-catalytic reaction showed a broad substrate scope, excellent functional group tolerance, and afforded the corresponding products in good to excellent yields. Compared with the previously reported use of photoredox/nickel dual catalysis in the construction of CC bonds, the methodology described herein was observed to be the first to allow for C-heteroatom bond formation.
- Subjects
BOND formation mechanism; COLD fusion; NICKEL catalysts; HOMOGENEOUS catalysis; CARBON-carbon bonds; ARYL iodides
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 13, p4962
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201500227