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- Title
Crystal and Electronic Structure of the Lithium-Rich Silver Silicide Li<sub>12</sub>Ag<sub>1− x</sub>Si<sub>4</sub> ( x=0.15).
- Authors
Slabon, Adam; Budnyk, Serhiy; Cuervo‐Reyes, Eduardo; Wörle, Michael; Verel, René; Nesper, Reinhard
- Abstract
Zintl phases: The new lithium‐rich Zintl phase Li12Ag1−xSi4 (x=0.15) contains the highly charged 16‐electron anion [AgSi2]7−. Chemical bonding is discussed based on electronic band structure analysis (see figure).
- Subjects
LITHIUM isotopes; SILICIDES; ENERGY-band theory of solids; FERMI energy; FERMI level; ELECTRONIC density of states
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 49, p16528
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201302574