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- Title
Preparation, Crystal Structure, and Magnetic Properties of a New Dithiolene Ligand, 1,3,2-Dithiazole-4-thione-5-thiolate, and its Metal Complex.
- Authors
Nakamura, Tadamitsu; Sasamori, Kota; Kodama, Takeshi; Kikuchi, Koichi; Fujita, Wataru
- Abstract
1, 3, 2, 4, 5, go! A new dithiolene ligand, 1,3,2 ‐ dithiazole ‐ 4 ‐ thione ‐ 5 ‐ thiolate (dttt−), which is a stable and diamagnetic monoanion, was prepared. Its tris(dithiolene) complex Cr(dttt)3⋅CS2 is octahedral and forms a dimer through intermolecular interatomic S⋅⋅⋅S and S⋅⋅⋅C contacts in its crystalline state. Magnetic measurements of the complex revealed paramagnetism with intradimer ferromagnetic and interdimer antiferromagnetic interactions.
- Publication
Chemistry - An Asian Journal, 2013, Vol 8, Issue 2, p348
- ISSN
1861-4728
- Publication type
Article
- DOI
10.1002/asia.201200912