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- Title
Self-Healing Molecular Crystals.
- Authors
Commins, Patrick; Hara, Hideyuki; Naumov, Panče
- Abstract
One of the most inevitable limitations of any material that is exposed to mechanical impact is that they are inexorably prone to mechanical damage, such as cracking, denting, gouging, or wearing. To confront this challenge, the field of polymers has developed materials that are capable of autonomous self-healing and recover their macroscopic integrity similar to biological organisms. However, the study of this phenomenon has mostly remained within the soft materials community and has not been explored by solid-state organic chemists. The first evidence of self-healing in a molecular crystal is now presented using crystals of dipyrazolethiuram disulfide. The crystals were mildly compressed and the degree of healing was found to be 6.7 %. These findings show that the self-healing properties can be extended beyond mesophasic materials and applied towards the realm of ordered solid-state compounds.
- Subjects
SELF-healing materials; MOLECULAR crystals; POLYMERS; SMART materials; MACROMOLECULES
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 42, p13028
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201606003