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- Title
Near-IR-Triggered, Remote-Controlled Release of Metal Ions: A Novel Strategy for Caged Ions.
- Authors
Atilgan, Ahmet; Tanriverdi Eçik, Esra; Guliyev, Ruslan; Uyar, T. Bilal; Erbas‐Cakmak, Sundus; Akkaya, Engin U.
- Abstract
A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.
- Subjects
LIGAND binding (Biochemistry); PHOTOCHEMISTRY; PHOTOSENSITIZERS; REACTIVE oxygen species; METAL ions
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 40, p10678
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201405462