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- Title
Improving Photocatalytic Performance through the Construction of a Supramolecular Organic Framework.
- Authors
Xu, Weiquan; Chao, Jin‐Yu; Tang, Bohan; Li, Zhan‐Ting; Xu, Jiang‐Fei; Zhang, Xi
- Abstract
A supramolecular organic framework‐type photocatalyst, named TM‐SOF, is constructed by the self‐assembly of cucurbit[8]uril and a tetra‐arm monomer containing four N, N'‐dimethyl 2,5‐bis(4‐pyridinium)thiazolo[5,4‐d]thiazole (MPT) moieties. Benefiting from the multivalent assembly, a photocatalytically active supramolecular MPT dimer can be stably formed in TM‐SOF. In addition, TM‐SOF exhibits better stability against temperature, substrate, and light irradiation. As a result, TM‐SOF shows a significantly improved performance for the photocatalytic aerobic oxidation of aryl boronic acids and thioethers. It is anticipated that this line of research will provide a facile approach for fabricating high‐performance supramolecular photocatalysis systems.
- Subjects
PHOTOCATALYTIC oxidation; BORONIC acids; SUPRAMOLECULAR chemistry; PHOTOCATALYSIS; SULFIDES; MOIETIES (Chemistry); CUCURBITURIL; SUPRAMOLECULAR polymers
- Publication
Chemistry - A European Journal, 2022, Vol 28, Issue 63, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202202200