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- Title
MCM-41-immobilised bidentate nitrogen platinum complex: a highly efficient and recyclable phosphine-free catalytic system for the hydrosilylation of olefins.
- Authors
Zhang, Hean; Liu, Jiaqin; Cheng, Shaojuan; Cai, Mingzhong
- Abstract
An MCM-41-immobilised bidentate nitrogen platinum complex (MCM-41-2N-Pt) was very conveniently synthesised from commercially available and cheap 3-(2-aminoethylamino)propyltrimethoxysilane by immobilisation on the mesoporous silica nanoparticles, MCM-41, followed by reaction with potassium chloroplatinite. It was found that the MCM-41-2N-Pt complex is a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane and can be easily recovered and reused several times without significant loss of activity.
- Subjects
PHOSPHINE; HYDROSILYLATION; ALKENES; PLATINUM; CATALYSTS; NANOPARTICLES; CHEMICAL reactions; MCM-41 (Mesoporous material)
- Publication
Journal of Chemical Research, 2012, Vol 36, Issue 4, p241
- ISSN
1747-5198
- Publication type
Article
- DOI
10.3184/174751912X13324196074823