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- Title
Revisiting the Saito Photochemical Reduction and the Development of a One-Pot Deoxygenation of Alcohols.
- Authors
Matsubara, Ryosuke; Shin, Yong ‐ Soon; Shimada, Toshiyuki; Hayashi, Masahiko
- Abstract
We have revisited the Saito photochemical reduction and established practical reaction conditions, under which the reduction of m-(trifluoromethyl)benzoates, derived from secondary and tertiary alcohols, proceeds selectively at high concentration to afford the corresponding alkane products in good yields without formation of alkenes. A one-pot deoxygenation of alcohols to alkanes has also been developed.
- Subjects
PHOTOCHEMICAL rearrangement; CHEMICAL reduction; TRIFLUOROMETHYL compounds synthesis; BENZOATES; CHEMICAL synthesis; ALKANES; ALKENES; DEOXYGENATION; OXIDATION of chemical alcohols
- Publication
Asian Journal of Organic Chemistry, 2014, Vol 3, Issue 10, p1054
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201402123