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- Title
Synthesis of Cu-BTC, from Cu and benzene-1,3,5-tricarboxylic acid (H<sub>3</sub>BTC), by a green electrochemical method.
- Authors
Nguyen Thu Phuong; Claudine Buess-Herman; Nguyen Thi Thom; Pham Thi Nam; Tran Dai Lam; Dinh Thi Mai Thanh
- Abstract
A metal organic framework (MOF) material based on Cu-BTC, which is formed from Cu and benzene-1,3,5-tricarboxylic acid (H3BTC), with 1D and 3D structures was synthesized under potential control. CuBTC 3D was electrodeposited at an applied potential of 5 V using tetrabutylammonium tetrafluoroborate (TBATFB) as electrolyte during 10-60 min. Hydration showed that the phase structure of Cu-BTC 3D did not change after a short time of immersing in water and that the specific surface area increased from 48 m² /g to 371 m² /g. In contrast, with a long time of hydration (more than 4 h), Cu-BTC was destroyed and a dehydration process could not recover the Cu-BTC structure.
- Publication
Green Processing & Synthesis, 2016, Vol 5, Issue 6, p537
- ISSN
2191-9542
- Publication type
Article
- DOI
10.1515/gps-2016-0096