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- Title
Sustainable and Green Production of Nanostructured Cellulose by a 2-Step Mechano-Enzymatic Process.
- Authors
Aulitto, Martina; Castaldo, Rachele; Avolio, Roberto; Errico, Maria Emanuela; Xu, Yong-Quan; Gentile, Gennaro; Contursi, Patrizia
- Abstract
Nanostructured cellulose (NC) represents an emerging sustainable biomaterial for diverse biotechnological applications; however, its production requires hazardous chemicals that render the process ecologically unfriendly. Using commercial plant-derived cellulose, an innovative strategy for NC production based on the combination of mechanical and enzymatic approaches was proposed as a sustainable alternative to conventional chemical procedures. After ball milling, the average length of the fibers was reduced by one order of magnitude (down to 10–20 μm) and the crystallinity index decreased from 0.54 to 0.07–0.18. Moreover, a 60 min ball milling pre-treatment followed by 3 h Cellic Ctec2 enzymatic hydrolysis led to NC production (15% yield). Analysis of the structural features of NC obtained by the mechano-enzymatic process revealed that the diameters of the obtained cellulose fibrils and particles were in the range of 200–500 nm and approximately 50 nm, respectively. Interestingly, the film-forming property on polyethylene (coating ≅ 2 μm thickness) was successfully demonstrated and a significant reduction (18%) of the oxygen transmission rate was obtained. Altogether, these findings demonstrated that nanostructured cellulose could be successfully produced using a novel, cheap, and rapid 2-step physico-enzymatic process that provides a potential green and sustainable route that could be exploitable in future biorefineries.
- Subjects
SUSTAINABILITY; HAZARDOUS substances; BALL mills; CELLULOSE synthase; CELLULOSE
- Publication
Polymers (20734360), 2023, Vol 15, Issue 5, p1115
- ISSN
2073-4360
- Publication type
Article
- DOI
10.3390/polym15051115