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- Title
Homo‐Helical Rod Packing as a Path Toward the Highest Density of Guest‐Binding Metal Sites in Metal–Organic Frameworks.
- Authors
Zhao, Xiang; Shimazu, Matthew S.; Chen, Xitong; Bu, Xianhui; Feng, Pingyun
- Abstract
Abstract: In porous materials, metal sites with coordinate solvents offer opportunities for many applications, especially those promoted by host–guest chemistry, but such sites are especially hard to create for Li‐based materials, because unlike transition metals, lithium does not usually possess a high‐enough coordination number for both framework construction and guest binding. This challenge is addressed by mimicking the functional group ratio and metal‐to‐ligand charge ratio in MOF‐74. A family of rod‐packing lithium–organic frameworks (CPM‐47, CPM‐48, and CPM‐49) were obtained. These materials exhibit an extremely high density of guest‐binding lithium sites. Also unusual is the homo‐helical rod‐packing in the CPM series, as compared to the hetero‐helical rod packing by helices of opposite handedness in MOF‐74. This work demonstrates new chemical and structural possibilities in developing a record‐setting high density of guest‐binding metal sites in inorganic–organic porous materials.
- Subjects
METAL-organic frameworks; POROUS materials; SOLVENTS; HOST-guest chemistry; COORDINATION number (Chemistry); FUNCTIONAL groups
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 21, p6316
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201802267