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- Title
Direct Time-Domain Observation of Conformational Relaxation in Gas-Phase Cold Collisions.
- Authors
Drayna, Garrett K.; Hallas, Christian; Wang, Kenneth; Domingos, Sergio R.; Eibenberger, Sandra; Doyle, John M.; Patterson, David
- Abstract
Cooling molecules in the gas phase is important for precision spectroscopy, cold molecule physics, and physical chemistry. Measurements of conformational relaxation cross sections shed important light on potential energy surfaces and energy flow within a molecule. However, gas-phase conformational cooling has not been previously observed directly. In this work, we directly observe conformational dynamics of 1,2-propanediol in cold (6 K) collisions with atomic helium using microwave spectroscopy and buffer-gas cooling. Precise knowledge and control of the collisional environment in the buffer-gas allows us to measure the absolute collision cross-section for conformational relaxation. Several conformers of 1,2-propanediol are investigated and found to have relaxation cross-sections with He ranging from σ=4.7(3.0)×10−18 cm2 to σ>5×10−16 cm2. Our method is applicable to a broad class of molecules and could be used to provide information about the potential energy surfaces of previously uninvestigated molecules.
- Subjects
GAS phase reactions; CHEMICAL relaxation; MICROWAVE amplifiers; COOLING; POTENTIAL energy
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 16, p5041
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201600030