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- Title
Iron-Catalyzed Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes.
- Authors
Jianhui Chen; Biao Cheng; Minyi Cao; Zhan Lu
- Abstract
The highly regio- and enantioselective iron-catalyzed anti-Markovnikov hydrosilylation of 1,1-disubstituted aryl alkenes was developed using iminopyridine oxazoline ligands to afford chiral organosilanes. Additional derivatization of these products lead to chiral organosilanols, cyclic silanes, phenol derivatives, and 3-substituted 2,3-dihydrobenzofurans.
- Subjects
IRON catalysts; HYDROSILYLATION; SUBSTITUTION reactions; ALKENES; DERIVATIZATION
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 15, p4744
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201411884