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- Title
Rhodium(III)-Catalyzed Transannulation of Cyclopropenes with N-Phenoxyacetamides through CH Activation.
- Authors
Zhang, Hang; Wang, Kang; Wang, Bo; Yi, Heng; Hu, Fangdong; Li, Changkun; Zhang, Yan; Wang, Jianbo
- Abstract
An efficient rhodium(III)-catalyzed synthesis of 2 H-chromene from N-phenoxyacetamides and cyclopropenes has been developed. The reaction represents the first example of using cyclopropenes as a three-carbon unit in rhodium(III)-catalyzed C(sp2)H activations.
- Subjects
RHODIUM; CLASS B metals; CYCLOPROPENE; CYCLOALKENES; ACETAMIDE
- Publication
Angewandte Chemie, 2014, Vol 126, Issue 48, p13450
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201408555