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- Title
Heterocyclic Derivatives of Fullerene C<sub>60</sub>. 1. Synthesis of New Fulleropyrazolines by the 1,3-Dipolar Cycloaddition of Nitrile Imines.
- Authors
Reinov, M. V.; Yurovskaya, M. A.; Davydov, D. V.; Streletskii, A. V.
- Abstract
New stable [6,6]-closed cycloadducts, fulleropyrazolines containing aryl, hetaryl, trifluoromethyl, and other substituents in the five-membered ring, have been obtained by the 1,3-dipolar cycloaddition of nitrile imines to C60. Two methods of generating nitrile imines in situ have been used, the dehydrohalogenation of the corresponding hydrazonoyl halides by the action of triethylamine and the thermal decomposition of 2,5-diaryltetrazoles.
- Subjects
HETEROCYCLIC compounds; FULLERENES; PYRAZOLONES; RING formation (Chemistry); IMINES; NITRILES; CHEMICAL reactions
- Publication
Chemistry of Heterocyclic Compounds, 2004, Vol 40, Issue 2, p188
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1023/B:COHC.0000027890.05668.07