We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
A Metal-Organic Framework with a Pore Size/Shape Suitable for Strong Binding and Close Packing of Methane.
- Authors
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming
- Abstract
Much effort has been devoted to develop new porous structures for methane storage. We report a new porous coordination framework showing exceptional methane uptakes (e.g. 263 v/ v at 298 K and 65 bar) and adsorption enthalpies (21.6 kJ mol−1) as high as current record holders functionalized by open metal sites. Computational simulations demonstrated that the hierarchical pore structure consisting of single-wall nanocages has suitable sizes/shapes and organic binding sites to enforce not only strong host-methane and methane-methane interactions but also dense packing of methane molecules.
- Subjects
MOLECULAR structure of metal-organic frameworks; PORE size (Materials); METHANE; BINDING sites; ADSORPTION (Chemistry)
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 15, p4674
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201511006