We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Tetrahedral Anion Cage: Self-Assembly of a (PO<sub>4</sub>)<sub>4</sub>L<sub>4</sub> Complex from a Tris(bisurea) Ligand.
- Authors
Wu, Biao; Cui, Fengjuan; Lei, Yibo; Li, Shaoguang; de Sousa Amadeu, Nader; Janiak, Christoph; Lin, Yue‐Jian; Weng, Lin‐Hong; Wang, Yao‐Yu; Yang, Xiao‐Juan
- Abstract
AC3‐symmetric tris(bisurea) ligand L assembles with PO43− ions to form the tetrahedral cage [(PO4)4L4]12−. The PO43− ions form the four vertices and each forms 12 NH⋅⋅⋅O hydrogen bonds with 6 urea groups. A unique trinuclear pinwheel‐like helical complex [(SO4)3L2]6− is formed from L and SO42− ions (see picture).
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 19, p5096
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201209930