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- Title
Transition‐Metal‐Free Upscaling of 2,5‐Furandicarboxylic Acid Synthesis and Investigation of the Reaction Mechanism.
- Authors
Lee, Tae Woo; Lee, Won Jung; Kim, Young Sug; Do, Taeyang; Choi, Ji‐Eun; Han, Young Kwang; Oh, Chunrim; Lee, Chi‐Wan; Yum, Eul Kgun; Yang, Jung Woon
- Abstract
An environmentally friendly oxidation system has proposed for the practical and scalable production of value‐added 2,5‐furandicarboxylic acid from 1 kg of 5‐hydroxymethylfurfural. The system is composed of a simple base, oxygen, and a green solvent, thereby providing a sustainable and economical approach to organic synthesis. To gain insight into the mechanism of this oxidation process, NMR spectroscopic analysis and kinetic study are used for the mechanistic investigation of this environmentally friendly oxidation process.
- Subjects
ORGANIC synthesis; ACIDS; OXIDATION
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 36, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202300903