We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
C–H Arylation of Benzene with Aryl Halides using H<sub>2</sub> and a Water‐Soluble Rh‐Based Electron Storage Catalyst.
- Authors
Yatabe, Takeshi; Tome, Tamon; Takahashi, Yukina; Matsumoto, Takahiro; Yoon, Ki‐Seok; Nakai, Hidetaka; Ogo, Seiji
- Abstract
This paper reports the first example of C−H arylation of benzene under mild conditions, using H2 as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh‐based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H2 is inactive during the radical transfer step, greatly reducing unwanted side reactions.
- Subjects
ARYL halides; ARYLATION; ELECTRONS; BENZENE; ELECTRON sources; CATALYSTS; BENZENE derivatives
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 69, p17326
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202102735