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- Title
Triphenylphosphine‐Based Covalent Organic Frameworks and Heterogeneous Rh‐P‐COFs Catalysts.
- Authors
Liu, Yubing; Dikhtiarenko, Alla; Xu, Naizhang; Sun, Jiawei; Tang, Jie; Wang, Kaiqiang; Xu, Bolian; Tong, Qing; Heeres, Hero Jan; He, Songbo; Gascon, Jorge; Fan, Yining
- Abstract
The synthesis of phosphine‐based functional covalent organic frameworks (COFs) has attracted great attention recently. Herein, we present two examples of triphenylphosphine‐based COFs (termed P‐COFs) with well‐defined crystalline structures, high specific surface areas, and good thermal stability. Furthermore, rhodium catalysts with these P‐COFs as support material show high turnover frequency for the hydroformylation of olefins, as well as excellent recycling performance. This work not only extends the phosphine‐based COF family, but also demonstrates their application in immobilizing homogeneous metal‐based (e.g. Rh‐phosphine) catalysts for application in heterogeneous catalysis.
- Subjects
RHODIUM catalysts; HETEROGENEOUS catalysis; CATALYST supports; CRYSTAL structure; HYDROFORMYLATION; HETEROGENEOUS catalysts
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 53, p12134
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202002150