We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Nouveaux types de sucres triazotés: triazènes et phénylimino-2-oxadiazoles-1,3,4. Communication préliminaire.
- Authors
Tronchet, Jean M. J.; Rachidzadeh, Faranak
- Abstract
Novel types of sugars bearing three nitrogen atoms: triazenes and 2-phenylimino-1, 3, 4-oxadiazoles. A series of aminodeoxysugars treated with p-nitrobenzenediazonium tetrafluoroborate led to the corresponding triazenes, each of which in chloroform solution existing as an equilibrium between its two tautomeric forms. The free energy of activation of the exchange of the proton between the two nitrogen atoms has been estimated by variable temperature 1H-NMR. measurements. Each triazenylsugar gave on acetylation an unique positional isomer bearing its acyl group on the nitrogen atom directly attached to the glycosyl group. Phenylsemicarbazones of two keto-sugars were oxidized with El Khadem's reagent (I2, HgO, MgO) to give the corresponding spiro-2-phenylimino-1, 3, 4-oxadiazoles.
- Publication
Helvetica Chimica Acta, 1976, Vol 59, Issue 8, p2855
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19760590823