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- Title
One‐Pot Synthesis of Axially and Centrally Chiral A‐type Nanogrids.
- Authors
Wei, Ying; Du, Xue; Huang, Wan‐Xin; Fu, Ming‐Yang; Zhang, Zheng; Zhong, Chun‐Xiao; Wang, Yi‐Ru; Ling, Hai‐Feng; Xie, Ling‐Hai; Huang, Wei
- Abstract
Comprehensive Summary: A novel type of A‐type nanogrids (AGs) with axial and central chirality was synthesized via Friedel‐Crafts gridization of thiophenes and difluorenyl biaromatic derivatives, yielding 9%—30%. Additionally, the effect of stereoisomers of 1,1'‐binaphthyl difluorenols (BINDFOH) was investigated to demonstrate that R/S‐BINDFOH is more advantageous for the synthesis of AGs than Mix‐BINDFOH. Furthermore, tests on OFET memory devices showed that AGs have a larger storage window, indicating potential for data storage applications.
- Subjects
DATA warehousing; STEREOISOMERS; ORGANIC chemistry; MEMORY testing; THIOPHENES; CHIRALITY
- Publication
Chinese Journal of Chemistry, 2023, Vol 41, Issue 22, p2969
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.202300274