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- Title
Synthesis of a C<sub>2</sub>-Symmetrical Tetrakis(arylethynyl) Cavitand and Formation of Hybrid Hydrogen-Bonded/Metal-Ligand Coordination Supramolecular Capsules.
- Authors
Nito, Yuki; Nakada, Keiko; Kobayashi, KENji; Yamanaka, Masamichi
- Abstract
A C2-symmetrical tetrakis(arylethynyl) cavitand was synthesized. Spontaneous formation of hybrid hydrogen bonded/metal-ligand coordination supramolecular capsules occurs upon mixing 1 with cis-coordinated Pt2+ or Pd2+ metal complexes. The hybrid supramolecular capsules encapsulated neutral guest molecules only in polar solvents.
- Subjects
CAVITANDS; HYDROGEN; SUPRAMOLECULAR chemistry; LIGANDS (Chemistry); POLAR solvents
- Publication
Asian Journal of Organic Chemistry, 2014, Vol 3, Issue 7, p762
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201402041